Предмет: Химия, автор: robreiner888

На полное сжигание смеси углерода и диоксида кремния израсходовали кислород массой 22,4 г. Какой объём 20%-ного раствора гидроксида калия (плотность равна 1,173 г/мл) может прореагировать с исходной смесью, если известно, что массовая доля углерода в ней составляет 70%?

Товарищи, помогите кто чем может. Благодарен буду всем.

Ответы

Автор ответа: Himi4ka
0
1)Записываем уравнения реакций:
Sio2+2KOH=K2SiO3+H2O
C+O2=Co2
2)Далее ищем кол-во вещества:
По формуле:n=m/Mr,где Mr- молярная масса.
n(O)=22.4/16*2=0.7моль (16*2-это молярная масса кислорода)
n(O)=n(C)=0.7 моль. т.к углерод и кислород в равном отношении,т.о коэффициентов перед ними нет.
Отсюда ищем массу С.
m(C)=n(C)*Mr=0.7*12=8.4г
3)Всего смесь=100% ,углерода в смеси 70,следовательно,SiO2=30%
m(SiO2)=8.4*30/70=3.6 г
4)Ищем кол-во вещества Оксида премния
n(SiO2)= по той же формуле: m(Sio2)/Mr(SiO2)=3.6/60=0.06 моль
5)n(KOH)=2n(SiO2),т.к перед KOH в уравнении коэффициент-2.
n(KOH)=0.06*2=0.12г
Ищем n(KOH) в растворе=0.12*56=6.72
6)m(KOH)в растворе=n* массовую долю=6.72*20/100=33.6г
7)мn(KOH)=m/плотность=33.6/1.173=28.64.
Ответ.28.64


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